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by Julian C. Gray |
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Crystallography:
Diamond has perhaps the most fascinating crystal morphology of any mineral.
Diamonds crystallize as octhedrons, cubes, or dodecahedrons and commonly
exhibit habits that contain two or more of these forms. Although
we find diamonds at the Earth’s surface, they form deep within the Earth.
They have a rapid and violent journey from their birthplace in the mantle
to the volcanoes in which they occur. Along the way the
pressure that allowed them to form is rapidly removed (Kirkley, 1998).
They then become unstable and begin to dissolve, leaving the surface of
many diamonds etched or pitted and their overall shape occasionally rounded.
Etched diamonds can also exhibit a cross figure on its faces. Whether through
growth or etching, another crystal form is sometimes observed: the hexoctahedron
(six faces on each of the octahedral faces). Other interesting features
are the etched pits found on the faces of diamonds. Since these are frequently
triangular, these etched pits are called trigons. The face of an octahedron
is a triangle. Trigons found on octahedrons are oriented such that the
point of its triangle is pointed in the opposite direction of point of
the triangle of the octahedral face. Figure 1 shows an octahedral
diamond crystal modified by a hexoctahedron (evidenced by the fact that
the triangular octahedron face really has six sides). Furthermore, this
drawing shows etched trigons. Notice that trigon and octahedron triangles
point in opposite directions (Sunagawa, 2005).
Physical properties:
Diamond is the hardest known mineral, H=10, and a specific gravity
of 3.51. Diamonds luster is adamantine and uncut crystals have a greasy
appearance. High refractive index (2.42) and dispersion. Color is pale
yellow or colorless, but may be found in many other colors.
Diamond has perfect octahedral cleavage {111}.
Chemistry:
Diamond is pure carbon. General Electric first synthesized diamond
in 1955 at pressures of 600,000 to 1,500,000 psi and temperatures of 750
to 2,750 degrees C. In 1967, GE also produced a hexagonal polymorph of
diamond that was later discovered in the Canyon Diablo
meteorite in Arizona. This hexagonal polymorph is lonsdaleite, which
has also been found in the Goalpara meteorite and in sands in various parts
of Russia (Bernard and Hyr?l, 2004).
Occurrence:
The most common geologic setting of diamonds is in diamond pipes, small
diameter volcanic features. The volcanic host rock is kimberlite, whose
magma type is generated deep within the earth’s mantle. This rock weathers
to a yellow rock near the surface (yellow ground), which gives way to a
darker fresh rock at depth (blue ground). Diamonds liberated by weathering
also accumulate in alluvial deposits (Klein, 2002).
Diamonds are found, but not formed, in kimberlite. In nature, diamond
forms at temperatures in excess of 1200 C (2200 F) and at pressures 44,000
times that of atmospheric pressure. These conditions are found only at
depths of 100 miles below the surface of the Earth. The two main rock types
in which diamond is formed are harzburgite and eclogite, both quite rare
igneous rock types. Harzburgite is composed of olivine, bronzite (an orthopyroxene),
and some pyrope (chrome- and magnesium-rich varieties). Harzburgitic diamonds
contain inclusions of olivine, broinzite, and pyrope. Harzburgitic diamonds
are more than 3 billion years old. Eclogite is a high pressure metamorphic
rock composed of garnet (almandine-pyrope variety) and omphacite (a sodium-rich
clinopyroxene). Diamond is so abundant in some of these eclogites that
is may comprise ten percent of the rock! An extremely fascinating mineral
inclusion that occurs in eclogite is diamond inclusions in garnet. They
are microscopic, but very unusual when you consider how they came to be.
Kimberlite is then derived from melt of eclogite or harzburgite and will
occasionally contain inclusions (xenoliths) of these diamond source rocks
(Kirkley, 1998).
The most productive diamond producing regions are southern Africa, Siberia, India, and Brazil. There are other minor occurrences in the United States: Murfeesboro, Arkansas; and Colorado and Wyoming (Klein, 2002).
Uses:
Diamonds extreme hardness, luster, and dispersion together with its
rarity make it one of the most sought after gemstones. Its hardness also
makes diamond useful in industry for abrasives and for saws and drills
(Klein, 2002).
References
and Suggested Reading:
Bernard, Jan H., and Hyr?l, Jaroslav, 2004, Minerals and Their Localities.
Granit Publishing House, Czech Republic, 807 p
.
Blackburn, W.H., and Dennen, W.H., 1997, Encyclopedia of Mineral Names.
The Canadian Mineralogist Special Publication 1, Mineralogical Association
of Canada, 360 p. Field, J.E., 1979, The Properties of Diamond. Academic
Press, Ltd., London, 674 p.
Harlow, George E., 1998, “What is a Diamond?” in Harlow, George E., The Nature of Diamonds. Cambridge University Press in association with the American Museum of Natural History, New York, p. 1-22.
Kirkley, Melissa B., 1998, “The Origin of Diamonds: Earth Processes”. in Harlow, George E., The Nature of Diamonds. Cambridge University Press in association with the American Museum of Natural History, New York, p. 48-65.
Klein, C., 2002, The 22nd edition of the Manual of Mineral Science (after J.D. Dana). John Wiley & Sons, Inc., New York, 681 p.641 p., CD-ROM.
Moore, Thomas, 2004, “A Collection of Diamond Crystals with Notes on Science, History, and Worldwide Localities of Diamonds”. Mineralogical Record, vol. 35, no. 1, p. 9-30 and 53-54.
Orlov, Yu. L. (ed.), 1973, The Mineralogy of the Diamond.John Wiley & Sons, New York, 235 p.
Seal, Michael, 1965, “Structure in Diamonds as Revealed by Etching”. American Mineralogist, vol. 50, p. 105-123. Sunagawa, Ichiro, 2005, Crystals: Growth, Morphology, and Perfection. Cambridge University Press, Cambridge, 295 p.
Diamond Crystal Diagrams from Goldschmidt's
Atlas der Krystalformen
Source: http://www.johnbetts-fineminerals.com/jhbnyc/diamdiag.htm
Photo courtesy of Julian C. Gray
Diamond octahedron (2.5 mm wide)
Udachnoe Kimberlite Pipe, Sakha, Russia
Julian C. Gray, Specimen (ex. Bill
Dameron)